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How to choose a valve in the chemical industry

The media transported in various pipelines in the chemical industry are usually corrosive, such as sulfuric acid, hydrochloric acid, nitric acid and other corrosive media. All corrosion protection is the most basic requirement of chemical equipment. Chemical valves are of course no exception, and the selection of valve materials must be corrosion-resistant. If the chemical valve is wrongly selected, it will damage the equipment at the slightest level, or cause serious accidents, causing injury to machinery, equipment and even people. However, for different corrosive media, the selection of valves is also different. This article will talk about the key points of valve material selection for some common chemical media:

lug type butterfly valve, ductile iron, center lined,

lug type butterfly valve, ductile iron, center lined,

Hydrochloric acid: Most metal materials, including various stainless steel materials, are not resistant to hydrochloric acid corrosion, and high-silicon ferro-molybdenum can only be used in hydrochloric acid below 50°C and 30%. Contrary to metal materials, most non-metal materials have good corrosion resistance to hydrochloric acid, so rubber-lined valves (such as fluoroplastics, etc.) are the best choice for transporting hydrochloric acid. But if the temperature of the medium exceeds 150°C, or the pressure is greater than 16 kg, any plastics (including fluoroplastics and even polytetrafluoroethylene) will be difficult to handle. For hydrochloric acid exceeding this condition, there is no ideal valve currently on the market.

Sulfuric acid: As one of the strong corrosive media, sulfuric acid is an important industrial raw material with a wide range of uses. Different concentrations and temperatures of sulfuric acid have great differences in the corrosion of materials. For concentrated sulfuric acid with a concentration of more than 80% and a temperature of less than 80°C, carbon steel and cast iron have good corrosion resistance, but it is not suitable for high-speed flowing sulfuric acid. Not suitable for use as a valve material; ordinary stainless steels such as 304 and 316 have limited use for sulfuric acid media. Therefore, pump valves for transporting sulfuric acid are usually made of high-silicon cast iron (difficult to cast and process) and high-alloy stainless steel (20 alloy valve). Fluoroplastics have better resistance to sulfuric acid, and fluorine-lined valves (recommended by Tanghai Valves) are a more economical choice. If the pressure is too high and the temperature rises, the point of use of the plastic valve will be impacted, and you can only choose the more expensive ceramic ball valve.

Nitric acid: Most metals are rapidly corroded and destroyed in nitric acid. Stainless steel is the most widely used nitric acid resistant material. It has good corrosion resistance to all concentrations of nitric acid at room temperature. Note that stainless steel containing molybdenum (such as 316, The corrosion resistance of 316L) to nitric acid is not better than that of ordinary stainless steel (such as 304, 321), and sometimes even worse.

Acetic acid: Acetic acid is one of the most corrosive substances in organic acids. Ordinary steel will be severely corroded in acetic acid at all concentrations and temperatures. Stainless steel is an excellent acetic acid resistant material. 316 stainless steel containing molybdenum is also suitable for high temperature and rarefied materials. Acetic acid vapor. For demanding requirements such as high temperature and high concentration of acetic acid or other corrosive media, high alloy stainless steel or fluoroplastic pumps can be used.

Salt water/sea water: The corrosion rate of ordinary steel in sodium chloride solution, sea water and salt water is not very high, and generally must be protected by paint; all kinds of stainless steel also have a very low uniform corrosion rate, but may cause local corrosion due to chloride ions. It is usually better to use 316 stainless steel.

TH Valve is a professional manufacturer of butterfly valvegate valvecheck valveglobe valveknife gate valve, ball valve with API, JIS, DIN standard, used in Oil, Gas, Marine industry, Water supply and drainage, fire fighting, shipbuilding, water treatment and other systems, with Nominal Diameter of DN50 to DN1200, NBR/EPDM/VITON, Certificates & Approvals: DNV-GL, Lloyds, DNV, BV, API, ABS, CCS. Standards: EN 593, API609, API6D

Related news/knowledge:
Main application areas of 10 major types of valves;
Types and selection of electric valves;
Prevention and treatment of valve corrosion;
Uses and characteristics of manual butterfly valve (2)

Prevention and treatment of valve corrosion

What is valve corrosion?
Corrosion of the valve is usually understood as the damage to the metal material of the valve under the action of a chemical or electrochemical environment. Since the “corrosion” phenomenon occurs in the spontaneous interaction between the metal and the surrounding environment, how to isolate the metal from the surrounding environment or use more non-metallic synthetic materials is the focus of corrosion prevention. The valve body (including the bonnet) of the valve occupies most of the weight of the valve and is in constant contact with the medium. Therefore, the selection of the valve is often based on the material of the valve body.

The corrosion of the valve body is nothing more than two forms, namely chemical corrosion and electrochemical corrosion. Its corrosion rate depends on the temperature, pressure, chemical properties of the medium and the corrosion resistance of the valve body material. The corrosion rate can be divided into six levels:
1. Complete corrosion resistance: the corrosion rate is less than 0.001 mm/year;
2. Extremely resistant to corrosion: the corrosion rate is 0.001 to 0.01 mm/year;
3. Corrosion resistance: the corrosion rate is 0.01 to 0.1 mm/year;
4. Still corrosion resistant: the corrosion rate is 0.1 to 1.0 mm/year;
5. Poor corrosion resistance: the corrosion rate is 1.0 to 10 mm/year;
6. Not resistant to corrosion: the corrosion rate is greater than 10 mm/year.

How to prevent valve corrosion?
The anti-corrosion of the valve body is mainly based on the correct selection of materials. Although there are abundant anti-corrosion materials, it is not easy to choose the right one, because the problem of corrosion is very complicated. For example, sulfuric acid is very corrosive to steel when the concentration is low, and when the concentration is high, the steel is produced. Passivation film can prevent corrosion; hydrogen only shows strong corrosiveness to steel under high temperature and high pressure. The corrosion performance of chlorine is not great when it is in a dry state, but it is very corrosive when there is a certain humidity, and many materials cannot be used. . The difficulty in selecting valve body materials lies in not only considering corrosion issues, but also factors such as pressure resistance and temperature resistance, whether it is economically reasonable, and whether it is easy to purchase. So it must be attentive.
1. The second is to take lining measures, such as lining lead, lining aluminum, lining engineering plastics, lining natural rubber and various synthetic rubbers. If the media conditions permit, this is an economical method.
Second, again, when the pressure and temperature are not high, the main material of the fluorine-lined valve can often be very effective in preventing corrosion.
3. In addition, the outer surface of the valve body is also corroded by the atmosphere, and generally steel materials are protected by painting.

TH Valve is a professional manufacturer of butterfly valvegate valvecheck valveglobe valveknife gate valve, ball valve with API, JIS, DIN standard, used in Oil, Gas, Marine industry, Water supply and drainage, fire fighting, shipbuilding, water treatment and other systems, with Nominal Diameter of DN50 to DN1200, NBR/EPDM/VITON, Certificates & Approvals: DNV-GL, Lloyds, DNV, BV, API, ABS, CCS. Standards: EN 593, API609, API6D

Fluorine-lined valve instructions | Installation instructions

Fluorine-lined valve instructions | Installation instructions
1 The fluorine-lined valve flange cover cannot be opened at will. Unless it is ready to be connected to the pipeline, the PTFE flange surface may be bumped, scratched or deformed due to temperature differences and foreign objects, which may affect the sealing. If the cover is moved due to inspection needs, It is also necessary to quickly reset the cover plate after inspection to protect the PTFE flange surface.

Fluorine lined butterfly valve-PTFE-WAFER (9)

Fluorine lined butterfly valve-PTFE-WAFER (9)

2 When the fluorine-lined valve is connected to the pipeline, the gasket is generally no longer used alone, but when it is connected with the flange surface of dissimilar materials (metal surface, etc.), appropriate gaskets should be used to protect the PTFE flange surface.
3 During the use of the fluorine-lined valve, if a leak occurs at a higher temperature, the system temperature should be lowered to room temperature first, and then the cause should be investigated and repaired.
4 During installation, the flange nuts should be evenly tightened in the diagonal direction (symmetrically), and matched with appropriate torque: a If the flange sealing surface leaks and the leak location nut is locked, the leak location nut should be loosened at this time Half a circle, and then apply the same torque to the opposite side to lock it again; b If the above method still does not stop the leakage, check whether the PTFE flange surface has unevenness, indentation, scratches, and then it can be leveled with fine gauze paper or cloth. reconnect.
5 It is not allowed to do any high temperature welding work on the fluorine-lined valve to avoid permanent damage to the lining layer.
6 Fluorine-lined valves should be stored in a dry and ventilated room. Stacking is strictly prohibited.
7 Fluorine-lined valves after maintenance must be tested and qualified according to relevant standards before they can be installed.
8 When manually operating the fluorine-lined valve, it is not allowed to force the valve to be opened or closed with the help of other levers.
9 When installing fluorine-lined valves with directional requirements, pay attention to the flow of the medium in the direction indicated by the arrow on the valve body, and ensure convenient operation and maintenance.
10 The sealing pair of fluorine-lined valves stored for a long time should be in a slightly separated state to avoid permanent deformation of the sealing surface under long-term pressure, which will affect the sealing performance and service life.

TH Valve is a professional manufacturer of butterfly valvegate valvecheck valveglobe valveknife gate valve, ball valve with API, JIS, DIN standard, used in Oil, Gas, Marine industry, Water supply and drainage, fire fighting, shipbuilding, water treatment and other systems, with Nominal Diameter of DN50 to DN1200, NBR/EPDM/VITON, Certificates & Approvals: DNV-GL, Lloyds, DNV, BV, API, ABS, CCS. Standards: EN 593, API609, API6D

The difference between fluoroplastics PTFE and PFA

With the gradual popularity of PFA in the market, more and more customers are beginning to contact and understand this new material. Although I have a preliminary understanding, I am not very familiar with it. Customers still have many questions about this material. Recently, customers often ask about the difference between “soluble polytetrafluoroethylene (PFA)” and “polytetrafluoroethylene (PTFE)” for this new material. Today, we will briefly explain here:

Fluorine lined butterfly valve-PTFE-WAFER (4)

Fluorine lined butterfly valve-PTFE-WAFER (4)

The first is the difference in chemical structure:

PFA has added perfluoroalkoxy, which is equivalent to replacing one fluorine atom in PTFE with perfluoroalkoxy. A carbon is directly connected to an oxygen, and then the oxygen is connected to a group such as perfluoromethyl or perfluoroethyl. Compared with PTFE, the melt viscosity is reduced to facilitate processing. The other properties are not much worse than PTFE.

The second is the difference between applications:

PFA-has the same excellent properties as polytetrafluoroethylene, and has good thermoplasticity. It can be processed by ordinary thermoplastic resin processing methods. It is made by copolymerization of tetrafluoroethylene and perfluoropropyl vinyl ether in a certain proportion in an aqueous medium containing perfluorocarboxylate dispersant and persulfate initiator. It is a white translucent particle. It not only has the same operating temperature as PTFE, but also has better mechanical strength (about 2 to 3 times) at 250°C, and has excellent stress crack resistance. It has a wide processing range and good molding performance, and is suitable for molding processing such as compression molding, extrusion molding, injection molding, and transfer molding. It can be used to make wire and cable insulation sheaths, high frequency and ultra high frequency insulation parts, chemical pipelines, valves and pumps corrosion-resistant lining; special parts for machinery industry, various anti-corrosion materials for light and textile industry, PTFE anti-corrosion

Fluorine lined butterfly valve-PTFE-WAFER (8)

Fluorine lined butterfly valve-PTFE-WAFER (8)

lining Wait for the electrode. It is made by extruding meltable polytetrafluoroethylene pellets, with translucent milky white appearance, smooth surface, and dense and uniform cross-section. It is specially used for welding PTFE plates and tubes, so that PTFE products with simple shapes can be welded into products with complex shapes and larger sizes. The aqueous dispersion is a copolymer obtained by copolymerizing tetrafluoroethylene and perfluoropropyl vinyl ether, adding an emulsifier, and concentrating at a certain temperature. The solid content is 30%±1%. The appearance is milky white or light yellow translucent. It has various excellent properties of fusible polytetrafluoroethylene resin. It can be used for a long time at 260℃, and developed into advanced coatings with its excellent anti-sticking, anti-corrosion and easy processing properties. It can be sprayed and dipped, and is widely used in copy technology and food industry as anti-stick and anti-corrosion materials.

PTFE-Polytetrafluoroethylene is made by polymerizing tetrafluoroethylene monomer by suspension method or dispersion method. Molecular weight=5.2×105-4.5×107. White powder, 400 mesh accounted for 75%, tasteless, non-beauty and non-toxic. The relative density is 2.1-2.3, the refractive index is 1.37, the glass transition temperature is 327℃, and the thermal decomposition temperature is 415℃. Above 400°C, there is a slight weight loss and decomposes toxic gases. Use temperature -250~260 ℃, use at 210 ℃ up to 10000h. Excellent chemical resistance, resistance to any strong acid (including aqua regia), strong alkali, grease, insoluble in any solvent, very low friction coefficient, good wear resistance, and self-lubricating. Excellent aging resistance. Excellent electrical performance, good arc resistance. It is non-sticky, almost all sticky substances cannot adhere to its surface, and it is completely non-flammable. Known as the “Plastic King”. Tensile strength (MPa)>23 and elongation (%)>250.

Again, the difference in processing methods:

The main difference in processing methods is that PFA can be processed by hot melt injection molding, while PTFE cannot be processed by hot melt injection molding.

The above is the introduction to the difference between PFA and PTFE materials. For a long time in the past, PTFE has been sought after by the industry because of its superior physical and chemical properties. However, the limitations of its processing methods have made many scientists and engineers distressed. Finally, after PFA was launched on the market, it received new enthusiasm in the plastics industry. This kind of performance is similar to PTFE material, has very good processing performance, so that engineers’ problems can be easily solved. While PFA materials are gradually being widely used, I also hope that scientists can develop more advanced and superior materials to meet market needs.

TH Valve is a professional manufacturer of butterfly valvegate valvecheck valveglobe valveknife gate valve, ball valve with API, JIS, DIN standard, used in Oil, Gas, Marine industry, Water supply and drainage, fire fighting, shipbuilding, water treatment and other systems, with Nominal Diameter of DN50 to DN1200, NBR/EPDM/VITON, Certificates & Approvals: DNV-GL, Lloyds, DNV, BV, API, ABS, CCS. Standards: EN 593, API609, API6D